Chemistry 401

Intermediate Inorganic Chemistry

University of Rhode Island

Fall 2013

Exam 1

1. Write the electron configuration (using rare gas notation for closed shells) and the ground state Term Symbol for the following: a) Sc; b) Sc+; c) Sc2+; d) Sc3+; e) Sc.

2. Write the Lewis dot structure, give the formal charges on all atoms, predict the molecular geometry, estimate of all bond angles, and give the likely hybrid orbital for the following: a) BrO2; b) BrO3; c) BrO2F3.

3. The Absolute Hardness of an atom is defined as η = ½(IP – EA), IP is the ionization potential and EA is the electron affinity. Predict the periodic trends of η and provide reasoning for your prediction.

4. Cr2 has an electron configuration of σ2π4δ4δ*2. What is the bond order and how many unpaired spins are predicted? Would you expect Cr2 to absorb light in the visible region of the spectrum? Why or why not?

 

 

Answers