Exam 3B, Spring 2001

1. Complete and balance the following reactions:

(a) C5H5N(aq) + H2O(l)

(b) C5H5N(aq) + HCl(aq)

(c) Co2+(aq) + H2O(l)

(d) Ca(OH)2(aq) + HF(aq)

(e) H3PO4(aq) + CaI2(aq)

(f) NO2(aq) + H2O(l)

(g) C6H5NH2(aq) + HOCl(aq)

2. What is the pH of a 0.0052 M solution of methylamine, CH3NH2, at 25 °C?

3. Indicate whether the following salts are acidic, basic, or neutral.

(a) NaNO3

(b) Ca(C2H3O2)2

(c) KHSO4

(d) Co(OH)2

(e) CsNO2

4. A buffer is prepared that is 0.40 M boric acid, H3BO3, and 0.50 M sodium dihydrogen borate.

(a) What is the pH of the buffer at 25 °C?

(b) 0.05 moles of perchloric acid is added to 1.0 L of the buffer prepared in part (a). What is the new pH?

5. Which is more soluble at 25 °C, magnesium fluoride or lithium phosphate?

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