Chemistry 112

By the units of the rate constant, the reaction must be second order:

CO(g) + NO2(g) → CO2(g) + NO(g)

so the general rate law is given by

Rate = k[CO]m[NO2]n

m + n = total order of reaction

Rate = M s–1 = k[ ]m+n

M s–1 = M–1s–1[M]m+n

M = [M]m+n–1

so

m + n – 1 = 1

or

m + n = 2.

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