2. Find all of the Russell-Saunders terms for the s1d1 electron configuration. Predict the energetic ordering of the different states.


L = 0 + 2 = 2, so ML = 2, 1, 0, -1, -2

S = ½ + ½ = 1 so MS = 1, 0, -1

Number of microstates = 
 
ML\MS
(s, d)
1
0
-1
2
(0+,2+)
(0+,2-) (0-,2+)
(0-,2-)
1
(0+,1+)
(0+,1-) (0-,1+)
(0-,1-)
0
(0+,0+)
(0+,0-) (0-,0+)
(0-,0-)
-1
(0+,-1+)
(0+,-1-) (0-,-1+)
(0-,-1-)
-2
(0+,-2+)
(0+,-2-) (0-,-2+)
(0-,-2-)

ML = 2, MS = 1 gives 3D (15 microstates)

ML = 2, MS = 0 gives 1D (5 microstates)

Energy ordering: 3D < 1D