2. Find all of the Russell-Saunders terms for the s1d1 electron configuration. Predict the energetic ordering of the different states.
L = 0 + 2 = 2, so ML = 2, 1, 0, -1, -2
S = ½ + ½ = 1 so MS = 1, 0, -1
Number of microstates =
ML\MS
(s, d) |
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2 |
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1 |
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0 |
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-1 |
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-2 |
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ML = 2, MS = 1 gives 3D (15 microstates)
ML = 2, MS = 0 gives 1D (5 microstates)
Energy ordering: 3D < 1D