Homework 2

Due Tuesday, Feb. 19, 2019 at 3:15 p.m. EST

For the following, show the two lowest energy Lewis structures (identify the lower energy structure), estimate the bond angles, give the point group, and give the predominant hybrid on the central atom.

a. azide ion, N3

b. perrhenate ion, ReO4

c. selenate ion, SeO42–

Answer

a. azide ion, N3

Lewis Structures:

N-N-N bond angle: 180°

Point Group: D∞h

Hybrid: sp

b. perrhenate ion, ReO4

Lewis Structures:

O-Re-O bond angle: 109.5°

Point Group: Td

Hybrid: sd3

c. selenate ion, SeO42–

Lewis Structures:

O-Se-O bond angle: 109.5°

Point Group: Td

Hybrid: sp3