Chemistry 112

The solubility product constant of calcium hydroxide was measured at several temperatures, as given below. Find ΔH° and ΔS° using a van't Hoff plot.

T (°C)Ksp T (K) 1/T (K–1) ln Ksp


105.5×10–6 283 0.00353 –12.11


204.8×10–6 293 0.00341 –12.25


303.2×10–6 303 0.00330 –12.65


402.7×10–6 313 0.00319 –12.82


502.5×10–6 323 0.00310 –12.90


601.9×10–6 333 0.00300 –13.17


701.5×10–6 343 0.00292 –13.41


801.5×10–6 353 0.00283 –13.41


901.2×10–6 363 0.00275 –13.63


 

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