Chemistry 112

This is a typical basic salt equilibrium problem:

NaCHO2(aq) Na+(aq) + CHO2(aq)

CHO2(aq) + H2O(l) HCHO2(aq) + OH(aq)

Kb = [HCHO2]e[OH]e                             [CHO2]e = 1.0×10–14/1.8×10–4 = 5.6×10–11

Initial0.050 0 0

Change–x +x +x

Equilibrium0.050 – x x x

Approximate? 0.050/5.6×10–11 = 8.9×108 Yes

5.6×10–11 = x2/0.050

x = 1.7×10–6 = [OH]e

pOH = –log[OH]e = –log(1.7×10–6) = 5.77

pH = 14.00 – pOH = 14.00 – 5.77 = 8.23

 

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