First change the mass to moles: 1.0 g HBr × 1 mol HBr/(1.0 g + 79.9 g) = 0.012 mol in 1.00 L
[HBr] = 0.012 M
(The pH of this strong acid in the absence of buffer would be pH = –log(0.012) = 1.92)
NaNO2(aq) → Na+(aq) + NO2–(aq)
HNO2(aq) + H2O(l) → ← H3O+(aq) + NO2–(aq)