Chemistry 112

HNO2(aq) + H2O(l) H3O+(aq) + NO2(aq)

Ka = [H3O+]e[NO2]e                           [HNO2]e



Initial0.0100 0 0

Change–x +x +x

Equilibrium0.0100 – x x x

We can use the per cent ionization to find the value of x:

x = [H3O+]e

α = [H3O+]e              [HNO2]init ×100%

or

[H3O+]e = α×[HNO2]init/100% = 19%×(0.0100)/100% = 0.0019 M

[NO2]e = [H3O+]e = 1.9×0–3 M

[HNO2]e = 0.0100 – x = 0.0100 – 0.0019 = 0.0081 M

 

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