PbO2(s) + Pb(s) → PbSO4(s) (pH = 1, sulfuric acid)
oxidation/reduction under an acidic environment
PbO2(s) + H2SO4(aq) + 2 H+(aq) + 2 e– → PbSO4(s) + 2 H2O(l)
Pb(s) + H2SO4(aq) → PbSO4(s) + 2 H+(aq) + 2 e–
PbO2(s) + Pb(s) + 2 H2SO4(aq) → 2 PbSO4(s) + 2 H2O(l)
This is known as a comproportionation reaction (two reactants lead to the same product).
This reaction is the one that drives the lead/acid battery in your automobile.