ClO3(aq) → ClO4(aq) + ClO2(aq)

basic environment

ClO3(aq) + H2O(l) → ClO4(aq) + 2 H+(aq) + 2 e

ClO3(aq) + 2 H+(aq) + 2 e → ClO2(aq) + H2O(l)

sum and eliminate common species

2 ClO3(aq) → ClO4(aq) + ClO2(aq)

This one could easily be balanced by inspection.